I posted many texts about Small Business Role Center in Microsoft Dynamics NAV 2013R2. If you need all on one place, you can use this toc:
Basic Information:
Setup:
Company Information: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/04/nav2013r2-small-business-role-center-company-information.aspx
General Ledger Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/05/nav2013r2-small-business-role-center-general-ledger-setup.aspx
Sales & Receivables Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/06/nav2013r2-small-business-role-center-sales-amp-receivables-setup.aspx
Purchase & Payables Seup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/08/nav2013r2-small-business-role-center-purchase-amp-payables-setup.aspx
Inventory Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/09/nav2013r2-small-business-role-center-inventory-setup.aspx
Fixed Assets Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/09/nav2013r2-small-business-role-center-fixed-assets-setup.aspx
Human Resources Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/10/nav2013r2-small-business-role-center-human-resource-setup.aspx
Other:
Bank & Payments / VAT Reporting: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/16/nav2013r2-small-business-role-center-bank-and-vat.aspx
When?